Producción Científica Profesorado

CO substitution vs CSi cleavage in the reactions of [(?-H)M3(CO)9(CCSiR3)] (M?=?Ru, R?=?Me, Ph; M?=?Os, R?=?Me) with tertiary phosphines: Experimental and theoretical studies.



Zuno Cruz, Francisco Javier

2019

VianneyGonzález-López, IndiraTorres-Sandovala, Ana L.Carrasco-González, AdonayElías-Jiménez, Marco A.Leyva, María J.Rosales-Hoz, JuliánCruz-Borbolla, Francisco J.Zuno-Cruz, GloriaSánchez-Cabrera, ChristianJardínez, (2019),CO substitution vs CSi cleavage in the reactions of [(?-H)M3(CO)9(CCSiR3)] (M?=?Ru, R?=?Me, Ph; M?=?Os, R?=?Me) with tertiary phosphines: Experimental and theoretical studies. Inorganica Chimica Acta, 492, 8-17. https://doi.org/10.1016/j.ica.2019.04.002


Abstract


This work describes the reactions of [(?-H)M3(CO)9(CCSiMe3)] (M?=?Ru, Os) with phosphines L (L?=?PMe3, PMe2Ph, PMePh2, and PPh3) which produce zwitterionic compounds [(?-H)M3(CO)9(HCCPR3)] where cleavage of the CSi and formation of CP bonds occurs. In the case of the ruthenium derivatives, CO substitution also occurs. Spectroscopic and structural characterization of the products is described.A theoretical analysis was carried out in order to understand the transformation pathway in the formation of the zwitterionic compounds.



Producto de Investigación




Artículos relacionados

Pentacoordination at Germanium by Transannular Bonding of Sulfur or Oxygen in an Eight-Membered Ring...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Synthesis and crystal structure of the N-8-(diphenyl-hydroxy-2-aminomethylpyridine)borane

Boron heterocycles derived from 2-guanidinobenzimidazole

Determination of Glucose by Flow Injection Analysis with Amperometric Detection at Fe(III)-(tris(3,5...

Hexacoordinated spirocyclic germanium(IV) complex: Synthesis and structural characterization

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipy...

Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying...