Producción Científica Profesorado

Ni(II), Pd(II) and Pt(II) complexes with SacNac tridentate ligand



González Montiel, Simplicio

2019

Ni(II), Pd(II) and Pt(II) complexes with SacNac tridentate ligand, Victoria M.Rendón-López, Ángel Josabad A. Castro, Jose C. Alvarado Monzón, Crispin Cristóbal, Gerardo G. Gonzalez, Simplicio G. Montiel, Oracio Serrano, Jorge A. Lopez, Polyhedron, 162 (2019) 207-218. https://doi.org/10.1016/j.poly.2019.01.021


Abstract


Organometallic and coordination nickel, palladium and platinum complexes, neutral and cationic, with general formula [M(?3-SacNac)X] and [M(?3-SacNac)L?][BPh4] (where M?=?Ni, Pd and Pt, X?=?Me, Cl, 1?6; M?=?Ni, X?=?N3, SMe, 7?8; M?=?Pd, X?=?I, 13; M?=?Ni and Pd, L??=?PPh3, 9?10; M?=?Ni and Pt, X?=?PMe3, dmso, 11?12) containing a new SacNac N,N,S-tridentate ligand [C6H5(S)CCH2C(N-CH2CH2NHC6H5)CH3] were synthetized and obtained as microcrystalline solids. Compounds 2?13 were fully characterized by elemental analysis, IR, 1D and 2D NMR spectroscopy. The structure of the ligand and eight complexes was determined by X-ray crystallographic analysis. The ligand can be both mono- or bi-deprotonated under mild reaction conditions. Results in Heck reaction and antiproliferative activities are reported.



Producto de Investigación




Artículos relacionados

Hypervalence at tin(IV) by transannular bonding of sulfur in an eight-membered ring: The case of dib...

Boron and transition metal compounds derived from 2-uroylbenzimidazole

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Hexacoordinated spirocyclic germanium(IV) complex: Synthesis and structural characterization

Understanding and Predicting Distorted T- versus Y-Geometries for Neutral Chromous Complexes Support...

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...

Determination of Glucose by Flow Injection Analysis with Amperometric Detection at Fe(III)-(tris(3,5...

Structural differences in eight- and ten-membered heterocyclic tin compounds displaying transannular...

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2